Baby Safety / Compounds / Chloroform

Is Chloroform safe for babies and kids?

High risk for kids

Infants are more vulnerable to Chloroform than children or adults due to immature hepatic/renal clearance, higher intake-to-body-weight ratio, rapid organ development, and increased gastrointestinal absorption.

What is chloroform?

Also known as: Trichloromethane, Trichlormethan, Trichloroform, Formyl trichloride.

IUPAC name
chloroform
CAS number
67-66-3
Molecular formula
CHCl3
Molecular weight
119.37 g/mol
SMILES
C(Cl)(Cl)Cl
PubChem CID
6212

Risk for babies

High risk

Infants are more vulnerable to Chloroform than children or adults due to immature hepatic/renal clearance, higher intake-to-body-weight ratio, rapid organ development, and increased gastrointestinal absorption.

Neonates and infants up to 12 months have incomplete blood-brain barrier development, immature Phase I/II metabolic enzymes (particularly CYP3A4, UGT1A1), and higher gastrointestinal permeability. Equivalent doses produce higher internal concentrations and longer residence times.

What to do: Minimize infant exposure through source control. For breastfeeding mothers: reduce maternal exposure. For formula-fed infants: use certified low-migration bottles and verified water sources. Consult pediatrician regarding any concerns.

Risk for pregnant and nursing people

Context-dependent

Pregnancy alters the metabolism and distribution of Chloroform, potentially increasing fetal exposure. The developing embryo/fetus is vulnerable during organogenesis (weeks 3-8) and neurological development. Placental transfer should be assumed.

No specific reproductive toxicity data identified, but pregnancy-specific safety data is limited for most chemicals. Precautionary minimization of exposure is recommended.

What to do: Minimize exposure during pregnancy and lactation. Consult healthcare provider regarding specific risks. Consider alternative products with lower hazard profiles.

Regulatory consensus

25 regulatory and scientific bodies have classified Chloroform. The classifications differ — that's the data.

AgencyYearClassificationNotes
IARC1999Group 2B (possibly carcinogenic to humans)IARC Monograph 73 (1999). Sufficient evidence in animals (hepatocellular carcinoma, renal tubular adenocarcinoma in rodents); inadequate evidence in humans. Mechanism: CYP2E1 oxidation to trichloromethanol → phosgene (highly reactive) → covalent protein and DNA binding. The principal disinfection byproduct in chlorinated water.
US EPA2001likely to be carcinogenic to humansEPA IRIS final assessment (2001). Liver and kidney cancer via both oral and inhalation routes. Oral slope factor 0.0061 per mg/kg-day; inhalation unit risk 2.3 × 10⁻⁵ per μg/m³. Chloroform is the most abundant trihalomethane (THM) in chlorinated drinking water; EPA MCLG 0, MCL 80 μg/L (total THMs).
EPA CTX / NIOSHpotential occupational carcinogen
EPA CTX / IRISB2 (Probable human carcinogen - based on sufficient evidence of carcinogenicity in animals)
EPA CTX / IRISLikely to be carcinogenic to humans
EPA CTX / IRISNot likely to be carcinogenic to humans
EPA CTX / NTP RoCReasonably Anticipated to be a Human Carcinogen
EPA CTX / IARCGroup 2B - Possibly carcinogenic to humans
EPA CTX / EPA OPPGroup B2 Probable Human Carcinogen
EPA CTX / CalEPAKnown human carcinogen
EPA CTX / GenetoxGenotoxicity: positive (Ames: negative, 8 positive / 7 negative reports)
EPA CTX / GenetoxGenotoxicity: positive (Ames: negative, 8 positive / 7 negative reports)
EPA CTX / Skin-EyeEye Irritation: Eye Irrit. 2 (score: high)
EPA CTX / Skin-EyeSkin Irritation: Skin Irrit. 2 (score: high)
EPA CTX / Skin-EyeEye Irritation: Eye irritation - category 2A (score: high)
EPA CTX / Skin-EyeSkin Irritation: Skin irritation - category 2 (score: high)
EPA CTX / Skin-EyeEye Irritation: Serious eye damage/eye irritation - Category 2 (score: high)
EPA CTX / Skin-EyeSkin Irritation: Skin corrosion/irritation - Category 2 (score: high)
EPA CTX / Skin-EyeEye Irritation: Category 1 (score: very high)
EPA CTX / Skin-EyeSkin Irritation: Category 2 (score: high)
EPA CTX / Skin-EyeSkin Irritation: Skin Irrit. 2 (score: high)
EPA CTX / Skin-EyeEye Irritation: Category 6.4A (Category 2A) (score: high)
EPA CTX / Skin-EyeSkin Irritation: Category 6.3A (Category 2) (score: high)
EPA CTX / Skin-Eyeskin sensitisation: in vivo (non-LLNA): Not likely to be sensitizing (score: low)
EPA CTX / Skin-Eyeskin sensitisation: in vivo (LLNA): Not likely to be sensitizing (score: low)

Regulators apply different standards of evidence — animal-data weighting, exposure-pattern assumptions, epidemiological power thresholds — which is why two scientific bodies can review the same data and reach different conclusions. The disagreement is the data.

Where kids encounter chloroform

  • Industrial FacilitiesManufacturing plants, Chemical storage areas, Waste treatment sites
  • Occupational EnvironmentsFactories, Warehouses, Transportation vehicles

Safer alternatives

Lower-risk approaches that achieve a similar outcome to Chloroform:

  • Water-based formulations where feasible
    Trade-offs: Longer drying time. May not achieve same performance in all applications.
    Relative cost: 0.8-1.5×
  • Bio-based solvents (d-limonene, ethyl lactate)
    Trade-offs: Higher cost. Flammability concerns with some bio-solvents.
    Relative cost: 2-5× conventional

Frequently asked questions

Is chloroform safe for kids?

Infants are more vulnerable to Chloroform than children or adults due to immature hepatic/renal clearance, higher intake-to-body-weight ratio, rapid organ development, and increased gastrointestinal absorption.

What products contain chloroform?

Chloroform appears in: Manufacturing plants (Industrial facilities); Chemical storage areas (Industrial facilities); Factories (Occupational environments); Warehouses (Occupational environments).

What should I do if my child is exposed to chloroform?

Minimize infant exposure through source control. For breastfeeding mothers: reduce maternal exposure. For formula-fed infants: use certified low-migration bottles and verified water sources. Consult pediatrician regarding any concerns.

Why do regulators disagree about chloroform?

Chloroform has been classified by 25 agencies including IARC, US EPA, EPA CTX / NIOSH, EPA CTX / IRIS, EPA CTX / IRIS, with differing conclusions. Regulators apply different standards of evidence (animal data weighting, exposure-pattern assumptions, epidemiological power thresholds), which is why two scientific bodies can review the same data and reach different conclusions. See the regulatory consensus table on this page for the full picture.

See Chloroform in the baby app

Look up products containing chloroform, compare to alternatives, and explore the full data record.

Open in baby View raw API data

Sources (3)

  1. IARC Monographs Volume 73: Chloroform (1999) — regulatory
  2. US EPA IRIS: Chloroform — Toxicological Review (Final) (2001) — regulatory
  3. ATSDR Toxicological Profile for Chloroform (1997) — report

Reference data, not professional advice. Aggregates publicly available regulatory and scientific data; not a substitute for veterinary, medical, legal, or regulatory advice. Why we built ALETHEIA →